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    Formic acid

    1. Molecular Structure

    Formic acid 2D Structure

    2. Chemical Identity

    PropertyValue
    IUPAC Nameformic acid
    Molecular FormulaCH2O2
    SMILESC(=O)O

    3. Chemical Properties

    PropertyValue
    Molecular Weight46.025 g/mol
    TPSA37.3 Ų
    LogP-0.2
    Formal Charge0

    4. Experimental Properties

    PropertyValue
    Boiling Point101 °C
    Melting Point8.3 °C
    Density1.220 at 20 °C/4 °C
    Solubilitygreater than or equal to 100 mg/mL at 70 °F (NTP, 1992)
    Flash Point156 °F (69 °C) (closed cup); 90% soln: 122 °F (50 °C) (closed cup)
    Autoignition Temp1004 °F (539 °C); 90% soln: 813 °F (434 °C)

    5. Supplier Suggestions

    SupplierWebsiteLocation
    Sigma Aldrich/MerckVisit MerckInternational
    LennoxVisit LennoxIreland
    Doc SolderVisit Doc SolderIreland

    6. GHS Safety & Hazards

    Signal Word
    Danger
    GHS PictogramGHS PictogramGHS PictogramGHS PictogramGHS Pictogram

    Hazard Statements

    • H226 (21.1%): Flammable liquid and vapor [Warning Flammable liquids]
    • H226: Flammable liquid and vapor [Warning Flammable liquids]
    • H290: May be corrosive to metals [Warning Corrosive to Metals]
    • H302 (18.3%): Harmful if swallowed [Warning Acute toxicity, oral]
    • H302: Harmful if swallowed [Warning Acute toxicity, oral]
    • H314 (99.7%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
    • H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
    • H318 (19.2%): Causes serious eye damage [Danger Serious eye damage/eye irritation]
    • H318: Causes serious eye damage [Danger Serious eye damage/eye irritation]
    • H331 (17.9%): Toxic if inhaled [Danger Acute toxicity, inhalation]
    • H331: Toxic if inhaled [Danger Acute toxicity, inhalation]
    • H332: Harmful if inhaled [Warning Acute toxicity, inhalation]
    • H335: May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
    • H361: Suspected of damaging fertility or the unborn child [Warning Reproductive toxicity]
    • H370: Causes damage to organs [Danger Specific target organ toxicity, single exposure]
    • H372: Causes damage to organs through prolonged or repeated exposure [Danger Specific target organ toxicity, repeated exposure]
    • H373: May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure]
    • H402: Harmful to aquatic life [Hazardous to the aquatic environment, acute hazard]

    Precautionary Statements

    • P203, P210, P233, P240, P241, P242, P243, P260, P261, P264, P264+P265, P270, P271, P280, P301+P317, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P308+P316, P316, P317, P318, P319, P321, P330, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)
    • P210, P233, P234, P240, P241, P242, P243, P260, P261, P264, P264+P265, P270, P271, P280, P301+P317, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P370+P378, P390, P403+P233, P403+P235, P405, P406, and P501 (click each P-code to see the statement)
    • P210, P233, P240, P241, P242, P243, P260, P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P308+P316, P316, P317, P319, P321, P330, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)
    • P210, P233, P240, P241, P242, P243, P260, P261, P264, P264+P265, P270, P271, P280, P301+P317, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P308+P316, P316, P317, P319, P321, P330, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)
    • P210, P233, P240, P241, P242, P243, P260, P261, P264, P264+P265, P270, P271, P280, P301+P317, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
    • P260, P261, P264, P270, P271, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P319, P321, P330, P363, P403+P233, P405, and P501 (click each P-code to see the statement)
    • P260, P261, P264, P271, P273, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P405, and P501 (click each P-code to see the statement)
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