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    Methyl ethyl ketone

    1. Molecular Structure

    Methyl ethyl ketone 2D Structure

    2. Chemical Identity

    PropertyValue
    IUPAC Namebutan-2-one
    Molecular FormulaC4H8O
    SMILESCCC(=O)C

    3. Chemical Properties

    PropertyValue
    Molecular Weight72.11 g/mol
    TPSA17.1 Ų
    LogP0.3
    Formal Charge0

    4. Experimental Properties

    PropertyValue
    Boiling Point79.59 °C
    Melting Point-86.67 °C
    Density0.805 at 20 °C/4 °C; 0.7997 at 25 °C/4 °C; 0.8255 at 0 °C/4 °C
    SolubilityConstant boiling mixture with water, BP 73.4 °C, contains 88.7% methyl ethyl ketone (MEK); Solubility of water in MEK is 12.5% at 25 °C
    Flash Point16 °F (-9 °C) (Closed cup)
    Autoignition Temp505 °C

    5. Supplier Suggestions

    SupplierWebsiteLocation
    Sigma Aldrich/MerckVisit MerckInternational
    LennoxVisit LennoxIreland
    Doc SolderVisit Doc SolderIreland

    6. GHS Safety & Hazards

    Signal Word
    Danger
    GHS PictogramGHS PictogramGHS Pictogram

    Hazard Statements

    • H225 (> 99.9%): Highly Flammable liquid and vapor [Danger Flammable liquids]
    • H225: Highly Flammable liquid and vapor [Danger Flammable liquids]
    • H303: May be harmful if swallowed [Warning Acute toxicity, oral]
    • H305: May be harmful if swallowed and enters airways [Warning Aspiration hazard]
    • H315: Causes skin irritation [Warning Skin corrosion/irritation]
    • H319 (> 99.9%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
    • H319: Causes serious eye irritation [Warning Serious eye damage/eye irritation]
    • H320: Causes eye irritation [Warning Serious eye damage/eye irritation]
    • H332: Harmful if inhaled [Warning Acute toxicity, inhalation]
    • H333: May be harmful if inhaled [Warning Acute toxicity, inhalation]
    • H335: May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
    • H336 (99.5%): May cause drowsiness or dizziness [Warning Specific target organ toxicity, single exposure; Narcotic effects]
    • H336: May cause drowsiness or dizziness [Warning Specific target organ toxicity, single exposure; Narcotic effects]
    • H370: Causes damage to organs [Danger Specific target organ toxicity, single exposure]
    • H371: May cause damage to organs [Warning Specific target organ toxicity, single exposure]
    • H372: Causes damage to organs through prolonged or repeated exposure [Danger Specific target organ toxicity, repeated exposure]

    Precautionary Statements

    • P210, P233, P240, P241, P242, P243, P260, P261, P264, P264+P265, P270, P271, P280, P301+P316, P301+P317, P302+P352, P303+P361+P353, P304+P317, P304+P340, P305+P351+P338, P308+P316, P319, P321, P331, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
    • P210, P233, P240, P241, P242, P243, P260, P261, P264, P264+P265, P270, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P308+P316, P317, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
    • P210, P233, P240, P241, P242, P243, P261, P264+P265, P271, P280, P303+P361+P353, P304+P340, P305+P351+P338, P319, P337+P317, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
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